URBANREC
New approaches for the valorisation of URBAN bulky waste into high added value RECycled products
Visible?Light?Driven Reduction of CO2 to CO and Its Subsequent Valorization in Carbonylation Chemistry and 13C Isotope Labeling
A convenient and safe approach in valorizing carbon monoxide (CO) produced from the photocatalytic reduction of carbon dioxide (CO2) has been investigated. Visible light was used to drive an optimized photocatalytic reduction using a ruthenium trisbipyridine complex as a sensitizer and a rhenium bipyridyl carbonyl complex as a catalyst to perform an efficient reduction of CO2 to CO, which was then simultaneously utilized in a palladium?catalyzed aminocarbonylation reaction at room temperature. This approach provides safe handling of the produced CO which also opens the way for a more efficient application of 13C?isotope and 14C?radioisotope?labeled CO2 in pharmaceutically relevant drug labeling.
» Author: Philipp Gotico , Antonio Del?Vecchio , Dr. Davide Audisio , Dr. Annamaria Quaranta , Dr. Zakaria Halime , Dr. Winfried Leibl , Prof. Ally Aukauloo
» Reference: doi:10.1002/[email protected]/(ISSN)1521-4095.hottopic-carbon
» Publication Date: 02/07/2018
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This project has received funding from the European Union's Horizon 2020 research and innovation program under grant agreement Nº 690103
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